M A T E R I A L S A F E T Y D A T A S H E E TSUPPLIER
M A T E R I A L S A F E T Y D A T A S H E E T
SECTION I - PRODUCT IDENTIFICATION |
| PRODUCT NAME: | Titanium ethoxide, liquid |
| PRODUCT CODE: | T-MSDS0075 |
| REFERENCE #: | 3087-36-3 |
| MANUFACTURER INFORMATION | |
| COMPANY NAME: | Materion Advanced Chemicals Inc. |
| 1316 W. St. Paul Avenue | |
| Milwaukee, WI 53233 | |
| EMERGENCY CONTACT: | CHEMTREC (800)424-9300 |
| ALTERNATE EMERGENCY CONTACT: | Materion Advanced Chemicals Inc. (414)289-9800 |
| CHEMICAL FAMILY: | Oraganometallic |
| CAS NUMBER: | 3087-36-3 |
| FORMULA: | Ti(OC2H5)4 |
| MOLECULAR WEIGHT: | 227.88 |
| SYNONYMS | |
|
Titanium ethoxide |
|
SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION |
| Hazardous Components (Chemical Name) | CAS # | Concentration | OSHA PEL | ACGIH TLV | Other Limits |
|---|---|---|---|---|---|
| Titanium ethoxide | 3087-36-3 | 85.0 -90.0 % | NE | NE | NE |
| Isopropoxy group | NA | 10.0 -18.0 % | NE | NE | NE |
SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS |
| PHYSICAL STATES: | [ ] Gas [ X ] Liquid [ ] Solid |
| MELTING POINT: | N.A. |
| BOILING POINT: | 153.00 C |
| SPECIFIC GRAVITY (WATER = 1): | 1.088 |
| DENSITY: | 1.08 - 1.10 g/cc at 20.0 C |
| VAPOR PRESSURE (VS. AIR OR MM HG): | |
| VAPOR DENSITY (VS. AIR = 1): | |
| EVAPORATION RATE (VS BUTYL ACETATE=1): | |
| SOLUBILITY IN WATER: | hydrolyzes |
| SOLUBILITY NOTES | |
| PERCENT VOLATILE: | N.A. |
| APPEARANCE AND ODOR | |
|
Clear to light yellow liquid; may have an ethanol-like odor. |
|
SECTION IV - FIRE AND EXPLOSION HAZARD DATA |
| FLASH PT: | N.A. Method Used: Unknown |
| EXPLOSIVE LIMITS: | LEL: NE UEL: NE |
| EXTINGUISHING MEDIA | |
|
USE: Use dry chemical or carbon dioxide exitinguishing agent |
|
| SPECIAL FIRE FIGHTING PROCEDURES | |
|
Firefighters must wear full face, self-contained breathing apparatus with full protective clothing to prevent contact with skin and eyes. Fumes from fire are hazardous. Isolate runoff to prevent environmental pollution. |
|
| UNUSUAL FIRE AND EXPLOSION HAZARDS | |
|
The flashpoint (PMCC) of freshly
made titanium ethoxide is 33-43 degC. If this
material is exposed to water or to moist air, it
will react, producing the alcohol associated with
the titanium. This will cause the flash point to
decrease. The flash point (PMCC) of a mixture of
80% (wt.) Titanium ethoxide and 20% (wt.)
water, after 20 minute exposure, is 24 degree C.
this water-exposed product should then be
considered as DOT flammable. Flammable Liquid. Vapor forms explosive mixture with air. |
|
| HAZARDOUS COMBUSTION PRODUCTS | |
SECTION V - REACTIVITY DATA |
| STABILITY: | Unstable [ ] Stable [ X ] |
| CONDITIONS TO AVOID - INSTABILITY | |
|
None |
|
| INCOMPATIBILITY - MATERIALS TO AVOID | |
|
Water, moisture, strong acids and bases |
|
| HAZARDOUS DECOMPOSITION OR BYPRODUCTS | |
|
May give off ethanol and isopropanol |
|
| HAZARDOUS POLYMERIZATION: | Will occur [ ] Will not occur [ X ] |
| CONDITIONS TO AVOID - HAZARDOUS POLYMERIZATION | |
|
None |
|
SECTION VI - HEALTH HAZARD DATA |
| HEALTH HAZARDS (ACUTE AND CHRONIC) | |
|
TITANIUM: This material is
generally considered to be physiologically inert.
There are no reported cases in the literature
where titanium as such has caused human
intoxication. The dusts of titanium or most
titanium compounds such as titanium oxide may be
placed in the nuisance category. (Sax, Dangerous
Properties of Industrial Materials, eighth
edition) INHALATION: Acute: CAUTION MAY BE POISONOUS BY INHALATION. May cause irritation to the lungs and respiratory tract. Chronic: No chronic health effects recorded. INGESTION: Acute: May cause severe irritation to the gastrointestinal tract. Chronic: No chronic health effects recorded. SKIN: Acute: CAUTION MAY BE POISONOUS BY SKIN ABSORBTION. May cause severe irritation. Chronic: May cause dermatitis. EYE: Acute: May cause severe irritation. May cause loss of vision. Chronic: No chronic health effects recorded. TARGET ORGANS: No target organs recorded. |
|
| CARCINOGENICITY: | NTP? No IARC Monographs? No OSHA Regulated? No |
| RECOMMENDED EXPOSURE LIMITS | |
|
See "Section II" |
|
| LD 50 / LC 50 | |
|
No toxicity data recorded |
|
| SIGNS AND SYMPTOMS OF EXPOSURE | |
|
INHALATION: May cause dizziness, a
sense of suffocation, sneezing, coughing and
difficulty breathing. INGESTION: May cause nausea, vomiting, abdominal pain, diarrhea, and possible burns to the mouth, throat and esophagus. SKIN: May cause redness, chemical burns, inflammation and itching. EYE: May cause redness, itching, inflammation, chemical burns and watering. |
|
| MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE | |
|
None recorded. |
|
| EMERGENCY AND FIRST AID PROCEDURES | |
|
INHALATION: Remove victim to fresh
air; keep warm and quiet; give oxygen if breathing
is difficult and seek medical attention. INGESTION: Give 1-2 glasses of milk or water; DO NOT induce vomiting; seek medical attention. SKIN: Remove contaminated clothing; brush material off skin; wash affected area with mild soap and water; seek medical attention if symptoms persist. EYE: Flush eyes with lukewarm water, lifting upper and lower eyelids, for at least 15 minutes. Seek medical attention if symptoms persist. |
|
SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE |
| STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED | |
|
Wear appropriate respiratory and
protective equipment specified in section
VIII-control measures. Isolate spill area,
provide ventilation and extinguish sources of
ignition. Vacuum up spill using a high efficiency
particulate absolute (HEPA) air filter and place
in a closed container for proper disposal. Take
care not to raise dust. Use non-sparking
tools. |
|
| WASTE DISPOSAL METHOD | |
|
Dispose of in accordance with local, state and federal regulations. |
|
| HAZARD LABEL INFORMATION: | |
| Store in cool, dry area Store in tightly sealed container Wash thoroughly after handling | |
| PRECAUTIONS TO BE TAKEN IN HANDLING | |
|
Titanium ethoxide may react with water or moisture. Handle and store in a controlled environment and inert gas such as argon. |
|
| PRECAUTIONS TO BE TAKEN IN STORING | |
| Titanium ethoxide may react with water or moisture. Handle and store in a controlled environment and inert gas such as argon. | |
| OTHER PRECAUTIONS | |
|
None |
SECTION VIII- CONTROL MEASURES |
| PROTECTIVE EQUIPMENT SUMMARY - HAZARD LABEL INFORMATION: | |
| NIOSH approved respirator Impervious gloves Safety glasses | |
| RESPIRATORY EQUIPMENT (SPECIFY TYPE) | |
|
NIOSH - approved air purifying respirator |
|
| EYE PROTECTION | |
|
Safety glasses |
|
| PROTECTIVE GLOVES | |
|
Rubber gloves |
|
| OTHER PROTECTIVE CLOTHING | |
|
Protective gear suitable to prevent contamination |
|
| VENTILATION | |
|
Local Exhaust: To maintain concentration at low exposure levels Special: Handle in a controlled environment Mechanical (Gen): Not recommended Other: Handle in an inert gas such as argon |
|
| WORK/HYGIENIC/MAINTENANCE PRACTICES | |
|
Implement engineering and work
practice controls to reduce and maintain
concentration of exposure at low levels. Use good
housekeeping and sanitation practices. Do not use
tobacco or food in work area. Wash thoroughly
before eating and smoking. Do not blow dust off
clothing or skin with compressed air. . |
SECTION IX - ADDITIONAL COMMENTS |
| No data available. |